Polymers

The following page of notes will cover:

  • Thermoplastics
  • Thermosetting Plastics
  • Elastomers


General comparisons of Thermoplastics vs Thermosetting plastics

Using these general rules will help you answer most questions relating to Polymers:

  • Thermoplastics can be reheated and reshaped where as thermosets only burn with heat, this gives them a wide range of appications
  • Both types of polymer can be recycled but thermoplastics are easier to recycle
  • Thermosetting polymers are heat resistant and more durable, they retain their shape when heated
  • Both types of polymers can be easily pigmented (coloured)
  • Thermoplastics are prone to UV degradation
  • Both polymers are heat and eletrical insulators
  • Both polymers are hygenic, easily cleaned and waterproof


Thermoplastics

Acrylic:

Advantages Disadvantages
  • Stiff
  • Hard
  • Durable
  • Good electrical insulator
  • Very brittle
  • Scratches easily
  • Splinters easily
  • Poor fatigue properties

Uses: CD cases, Car light cases, Baths



Polyethylene (PE):

Advantages Disadvantages
  • Good electrical insulator
  • Chemical resistant
  • Flexible
  • Colour fades over time/damaged by UV light
  • Can break under stress
  • Takes a long time to bio-degrade

Uses: Buckets, bowls, Cable insulation, bottles



Polyethylene terephthalate (PET):

Advantages Disadvantages
  • Good alcohol and oil barrier
  • Weather resistant
  • Can be made transparent
  • Inert/non-toxic
  • Stiff/tough/hard
  • Available in a range of colours
  • Can discolour from UV light
  • Needs to be treated when used for food containers
  • Susceptible to heat degradation

Uses: Fizzy drinks bottles, washing up bottles, fibres for clothing



Polyvinyl Chloride (PVC):

Advantages Disadvantages
  • Good chemical resistance
  • Weather resistant
  • Stiff/tough/hard
  • Available in a range of colours
  • Can discolour from UV light
  • Brittle
  • Easily scratched
  • Difficult to recycle

Uses: Pipes, guttering, electrical insulation, floor coverings



Polypropylene (PP):

Advantages Disadvantages
  • Lightweight
  • Hard
  • Impact resistant
  • Chemical resistant
  • Can discolour from UV light
  • Oxidation can cause problems
  • Not heat resistant
  • Difficult to paint

Uses: Medical syringes, carpets, kitchenware



Acrylonitrile Butadiene Styrene (ABS):

Advantages Disadvantages
  • Good chemical resistance
  • Hard
  • Tough/durable
  • Heat resistant
  • Naturally good finish
  • Can discolour from UV light
  • Poor solvent resistance

Uses: Mobile phones, safety helmets, pipes




Thermosetting plastics

Epoxy resin:

Advantages Disadvantages
  • Corrosion resistant
  • Electrical insulator
  • Good bond qualities
  • Causes health issues/toxic fumes
  • Brittle

Uses: Adhesives, paints and coatings, electronics



Urea formaldehyde:

Advantages Disadvantages
  • Strong
  • Hard
  • Heat resistant
  • Good electrical insulator
  • Can emit toxic vapours during manufacture
  • Brittle

Uses: Electrical fittings, handles, control knobs, domestic appliance components



Polyester resin:

Advantages Disadvantages
  • Good electrical insulator
  • Heat resistant
  • Hard
  • Cost effective
  • Short shelf life
  • Emissions are harmful
  • Brittle unless treated

Uses: Glass reinforced boats and cars, garden furniture, castings




Elastomers

Rubber:

Advantages Disadvantages
  • Waterproof
  • Renewable
  • Chemically resistant
  • Elasticity
  • Good electrical insulator
  • Shock absorbent
  • Expensive
  • Can be disfigured
  • Slow and time consuming to produce

Uses: Car tires, matting/flooring, medical gloves

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